Specifications
Surface Treatments
Certifications
- ISO 9001 - 2015 Certified
- PED 2014/68/EC
- NACE MR0175/ISO 15156-2
- NORSOK M-650
- DFAR
- MERKBLATT AD 2000 W2/W7/W10
Hiduron 191 (UNS C72420, NES 835, DEF STAN 02-835) is the proven splash-zone riser bolting grade on North Sea and Gulf of Mexico offshore platforms, with over 15 years of in-service performance on production-riser, export-riser and conductor-tieback bolting. The Cu-Ni-Al matrix carries seawater corrosion, splash-zone wet/dry cycling and biofouling resistance at a yield strength that conventional cupronickel cannot reach. NACE MR0175 sour-service compliance and hydrogen embrittlement immunity are the decisive selection drivers on platforms operated by BP, Shell, Equinor, ConocoPhillips and Chevron and on EPC packages delivered by Subsea7, Saipem and McDermott.
Splash-zone riser bolting carries the most punishing duty in the offshore portfolio: wet/dry tidal cycling, chloride saturation, biofouling pressure, cathodic protection at the platform leg and sour service on the export side. Hiduron 191 holds capacity through all five drivers without the chloride crevice attack that excludes austenitic and duplex stainless from the splash zone and without the NACE MR0175 hardness exceedance that excludes standard high-strength carbon steel and Monel K-500 from sour-service riser duty. The historical in-service record on North Sea and Gulf of Mexico platforms is the operator-side validation that the spec carries through 15 to 20 year platform-life service.
Hiduron 130 (UNS C72400) is a copper-nickel-aluminium-iron precipitation-hardened cupronickel with roughly 14 to 15.5 percent nickel, 2.7 to 3.4 percent aluminium and 1 to 2 percent iron in a copper matrix. Hiduron 191 (UNS C72420) carries the same nickel envelope with a manganese addition of 4 to 5 percent and a lower aluminium and iron level, which lifts the strength response while preserving NACE MR0175 compliance. The aluminium is the gamma-prime former: it pairs with the nickel during age to precipitate the Ni3Al strengthening phase that is the entire reason both grades carry yield strengths above any conventional cupronickel.
| Element | Hiduron 130 typical, percent | Hiduron 191 typical, percent | Role |
|---|---|---|---|
| Copper (Cu) | balance (~80 to 82) | balance (~76 to 78) | Matrix; seawater corrosion resistance |
| Nickel (Ni) | 14.0 to 15.5 | 14.0 to 15.5 | Strengthening partner for gamma-prime Ni3Al |
| Aluminium (Al) | 2.7 to 3.4 | 1.5 to 2.5 | Gamma-prime former; precipitation hardening |
| Iron (Fe) | 1.0 to 2.0 | 0.5 to 1.5 | Grain refinement; corrosion modifier |
| Manganese (Mn) | up to 0.75 | 4.0 to 5.0 | Solid-solution strengthening (191) |
| Silicon (Si) | up to 0.10 | up to 0.10 | Deoxidation residual |
| Lead (Pb) | up to 0.02 | up to 0.02 | Tramp limit for hot workability |
| Carbon (C) | up to 0.05 | up to 0.05 | Tramp limit |
Both Hiduron grades are supplied in the solution-annealed-plus-aged condition. Hiduron 130 develops tensile 740 to 850 MPa with 0.2 percent proof stress at least 480 MPa and elongation A5 at least 18 percent. Hiduron 191 develops tensile 820 to 1000 MPa with 0.2 percent proof stress at least 580 MPa and elongation A5 at least 15 percent. Both grades hold hardness below the NACE MR0175 sour-service limit of 286 HBW / 28 HRC when the age is controlled correctly. Magnetic permeability stays below 1.005 mu_r in both grades, which is the value that qualifies them for naval mine-countermeasures and submarine applications where stainless steels and standard Monel grades are excluded.
| Property | Hiduron 130 | Hiduron 191 | Test condition |
|---|---|---|---|
| Tensile strength (Rm) | 740 to 850 MPa | 820 to 1000 MPa | RT, SA+aged |
| 0.2 percent proof stress (Rp0.2) | ≥480 MPa | ≥580 MPa | RT, SA+aged |
| Elongation A5 | ≥18 percent | ≥15 percent | RT, longitudinal |
| Hardness (HV) | 240 to 280 | 270 to 320 | RT, Vickers |
| NACE MR0175 hardness ceiling | n/a (not NACE) | ≤28 HRC / ≤286 HBW | Sour-service limit |
| Charpy V impact (RT) | ≥60 J | ≥40 J | RT, longitudinal |
| Magnetic permeability | <1.005 mu_r | <1.005 mu_r | Non-magnetic, naval qualified |
| Density | 8.85 g/cm3 | 8.65 g/cm3 | Calculated |
The Hiduron family combines seawater corrosion and biofouling resistance of conventional 70/30 cupronickel with the strength response of gamma-prime precipitation hardening. The decisive value drivers are: NACE MR0175 sour-service compliance at high yield strength, hydrogen embrittlement immunity in cathodically protected subsea service, non-magnetic response below 1.005 mu_r for naval qualification, anti-galling behaviour against stainless and tungsten-carbide running faces, and anti-biofouling response that suppresses marine growth on long-immersion components. Standard Monel K-500 carries higher hardness than NACE MR0175 will allow at the strength levels that subsea connector and platform bolting require, which is the gap Hiduron 191 fills.
The standard cycle is solution-anneal at 900 to 950 deg C, hold one hour every 25 mm of section, then water quench to freeze the gamma-prime formers in solid solution. The age follows at 475 to 525 deg C for 3 to 6 hours then air cool. The age develops the Ni3Al strengthening precipitate that lifts the yield strength to the specification floor. Age temperature is the controlling variable: below 475 deg C the precipitate is under-developed and room-temperature yield falls below specification; above 525 deg C the precipitate over-coarsens and tensile drops. For NACE MR0175 sour-service bolting the age cycle is controlled to land hardness below 286 HBW / 28 HRC, and the hardness reading on the mill test certificate is the compliance evidence.
Hiduron 130 and Hiduron 191 are welded with matched-composition Cu-Ni-Al filler under inert-gas shielding using gas tungsten arc with argon shield. Preheat is 100 to 150 deg C and inter-pass temperature is controlled below 250 deg C to protect the heat-affected-zone toughness. The filler chemistry matches the parent gamma-prime response so the joint develops comparable strength after a post-weld age at 475 to 525 deg C. On naval and subsea bolting, post-weld solution-anneal followed by full age is standard to restore parent properties through the weld. Inspection follows ISO 5817 quality level B visual, dye-penetrant on cap and root, and ultrasonic on butt joints above 25 mm. On Hiduron 191 sour-service welds, hardness traverse across weld plus HAZ plus parent verifies hardness stays below 286 HBW / 28 HRC at every point.
Hiduron 130 is the mid-strength Cu-Ni-Al grade specified into subsea hydraulic connectors and general marine bolting to DTD 900/4805. Hiduron 191 steps up the strength envelope and adds NACE MR0175 sour-service compliance, which is why it is the controlling spec on naval and splash-zone bolting. Monel K-500 carries the same gamma-prime mechanism in a nickel-copper matrix but exceeds the NACE MR0175 hardness ceiling at full strength specification. Nickel Aluminium Bronze (UNS C95400) is a different alloy family (Cu-Al-Ni-Fe casting alloy) with a different strengthening mechanism; it is not interchangeable with Hiduron.
| Grade | UNS | Service envelope | When to specify |
|---|---|---|---|
| Monel K-500 | N05500 | Subsea instruments, gauges | Step UP to Hiduron 191 when NACE MR0175 hardness limits exclude K-500 |
| Hiduron 191 | C72420 | Naval, subsea, splash zone, sour service | Highest-strength NACE-compliant Cu-Ni-Al; non-magnetic |
| Hiduron 130 | C72400 | Subsea hydraulic connectors, marine | Mid-strength Cu-Ni-Al; subsea connector flagship grade |
| Nickel Aluminium Bronze (NAB) | C95400 | Propellers, marine valves | Different alloy family; not interchangeable with Hiduron |
| 70/30 Cupronickel | C71500 | Seawater piping | Lower strength; Hiduron replaces it where structural load matters |
The Hiduron family is specified into eight primary service areas across subsea, naval and marine sectors. Each application page below sets out the selection drivers, fastener form-factor mix, governing standards and inspection regime for that service.
TorqBolt supplies Hiduron 130 and Hiduron 191 across the bolting and machined-component form range that the Cu-Ni-Al alloy class is commercially available in. Plate, sheet, tubing, seamless pipe, fittings and flanges are not commercial Hiduron forms and are not supplied. Every order is supplied with EN 10204 type 3.1 mill test certificate by default, with type 3.2 third-party witness on call-out.
TorqBolt supplies Hiduron 130 (UNS C72400) and Hiduron 191 (UNS C72420) bolting and machined components worldwide from Mumbai head office and Rajkot production plant. EN 10204 type 3.1 mill test certificate by default; type 3.2 with Lloyd's Register, DNV, BV, SGS or TUV witness inspection on call-out. NACE MR0175 hardness certificate on call-out for Hiduron 191 sour-service orders. Send your enquiry →
Q. Why is Hiduron 191 specified for splash-zone riser bolting on offshore platforms?
The splash zone combines wet/dry tidal cycling, chloride saturation, biofouling, cathodic protection and sour service on the export side. Hiduron 191 holds capacity through all five drivers. Conventional austenitic and duplex stainless suffer chloride crevice attack in this band. Carbon steel and Monel K-500 exceed the NACE MR0175 hardness ceiling at the yield strength the riser bolting spec requires. Hiduron 191 is the only grade that closes the gap.
Q. What is the proven in-service record for Hiduron 191 riser bolting?
Over 15 years of in-service performance on North Sea and Gulf of Mexico offshore platform production risers, export risers and conductor-tieback bolting. The operator-side validation across platforms operated by BP, Shell, Equinor, ConocoPhillips and Chevron is the historical anchor for the specification on new-build and brownfield riser packages.
Q. Is Hiduron 191 riser bolting NACE MR0175 compliant?
Yes. Hiduron 191 is qualified to NACE MR0175 / ISO 15156 for sour-service bolting provided hardness is controlled below 286 HBW / 28 HRC, which the standard solution-anneal plus age cycle achieves. The mill test certificate carries the hardness reading per stud or bolt as the NACE compliance evidence.
Q. Do you supply matched-grade nuts and washers for riser bolting?
Yes. Hiduron 191 nuts, heavy hex nuts and washers from the same heat lot as the studs are supplied as the matched companion hardware. Same-heat-lot certification is standard practice on platform riser procurement.
Q. What inspection regime do you run on riser bolting?
EN 10204 type 3.1 mill test certificate by default with chemistry, mechanicals, hardness and dimensional report. EN 10204 type 3.2 with Lloyd's Register, DNV, BV, SGS or TUV third-party witness on call-out, plus NACE MR0175 hardness certification on every bolt. Visual, dye-penetrant and dimensional inspection per project ITP.